One pot application of a green chemistry-based finish for cotton fabric, providing hydrophobic, flame retardant, and antimicrobial properties.

Fluorinated and formaldehyde-based compounds impart excellent hydrophobicity and flame-retardant properties to cotton fabrics. However, they come with various health and environmental risks. A novel hydrophobic, flame retardant, and antimicrobial finishing agent free from fluorine and formaldehyde was synthesized. The diammonium phosphate octadecyl citrate (DAPOC) was synthesized by using stearic acid (octadecanoic acid), citric acid (propane-1,2,3-tricarboxylic acid), and diammonium hydrogen phosphate. It was grafted onto the cotton fabrics by employing the conventional pad-dry-cure method. The results indicated that this newly developed finish could be chemically bonded to cotton fabrics through C-O-C covalent bonds. The contact angle of the cotton fabric finished with a 12% concentration of the finishing agent reached 151.9°. Additionally, the finished cotton fabrics displayed evident flame-retardant properties. After undergoing 20 laundering cycles, DAPOC maintained strong hydrophobic and flame-retardant characteristics, demonstrating its durability. The chemical structure of DAPOC was verified by nuclear magnetic resonance spectroscopy (1H-NMR). The thermogravimetric analysis confirmed the flame-retardant nature of the treated cotton fabric samples. Scanning electron microscopy (SEM), Energy dispersive X-ray analysis (EDX), and Fourier-transform infrared spectroscopy (FTIR) results demonstrated the successful grafting of the newly created finish onto the cotton fiber. X-ray diffraction (XRD) spectra depicted that the crystalline structure of finished cotton fabric remained mostly unaltered. Furthermore, the finished cotton fabric exhibited commendable antimicrobial properties due to the inclusion of citric acid.

A comprehensive review of the current progresses and material advances in perovskite solar cells.

Recently, perovskite solar cells (PSCs) have attracted ample consideration from the photovoltaic community owing to their continually-increasing power conversion efficiency (PCE), viable solution-processed methods, and inexpensive materials ingredients. Over the past few years, the performance of perovskite-based devices has exceeded 25% due to superior perovskite films achieved using low-temperature synthesis procedures along with evolving appropriate interface and electrode-materials. The current review provides comprehensive knowledge to enhance the performance and materials advances for perovskite solar cells. The latest progress in terms of perovskite crystal structure, device construction, fabrication procedures, and challenges are thoroughly discussed. Also discussed are the different layers such as ETLs and buffer-layers employed in perovskite solar-cells, seeing their transmittance, carrier mobility, and band gap potentials in commercialization. Generally, this review delivers a critical assessment of the improvements, prospects, and trials of PSCs.

Solution processed high performance perovskite solar cells based on a silver nanowire-titanium dioxide hybrid top electrode.

Longer silver nanowires (AgNWs) > 50 µm and even 90 µm in length have been produced via a polyol method by just changing the stirring speed at a temperature of 130 °C. As-synthesized longer AgNWs are further utilized to construct transparent conductive AgNWs films by a facile drop-casting technique that attained a sheet resistance of 14.5 Ω sq-1 and transmittance over 85%, which is higher than ITO film. The use of a AgNWs/TiO2 hybrid electrode decreases the sheet resistance to 8.3 Ω sq-1, which is attributed to the enhancement of connections between AgNWs by filling the empty spaces between nanowires and TiO2 nanoparticles. Transparent perovskite solar cells (PSCs) on the basis of these AgNWs and AgNWs/TiO2 hybrid top electrodes were made and examined. Due to the light scattering nature of TiO2 nanoparticles, optical transmittance of the AgNWs/TiO2 hybrid electrode enhances to some extent after the coating of a TiO2 layer. Both cell efficiencies and stability of the PSCs are enhanced by using the AgNWs/TiO2 top electrode. A power conversion efficiency (PCE) of 10.65% was attained for perovskite devices based on only the AgNW electrode with a sheet resistance of 14.5 Ω sq-1. A PCE of 14.53% was achieved after coating with TiO2 nanoparticles, indicating the layer effect of TiO2 coating.

Correction: Solution processed high performance perovskite solar cells based on a silver nanowire-titanium dioxide hybrid top electrode.

[This corrects the article DOI: 10.1039/D2RA06778A.].